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曹心德(Cao Xinde)
特聘教授
电子邮件：xdcao@sjtu.edu.cn
办公室电话：021-54743926
办公地点：上海交通大学绿色环境楼
团队网站：http://gsgr.sjtu.edu.cn/CN/Default.aspx

研究方向

1. 土壤地下水污染修复技术及应用

2. 土壤地下水环境多介质界面传输

3. 土壤生物炭固碳及生态环境效应

4. 绿色友好型环境多功能修复材料

个人简历


  • 1998年毕业于中国科技大学化学系，获博士学位
  •  1998-2000 南京大学bwin必赢讲师
  •  2000-2003 美国University of Florida 博士后
  •  2003-2005 美国Stevens Institute of Technology 博士后
  •  2005-2009 美国University of Florida 土壤与水科学系 研究员
  •  2009年至今 bwin必赢 教授、长聘教授、特聘教授

上海交通大学特聘教授、博士生导师，bwin必赢常务副院长，土壤地下水污染修复技术研究所所长。上海市“浦江人才”计划获得者，中国高被引学者，全球高被引用科学家。国际SCI期刊Chemosphere副主编、Environmental Science and Pollution Research、环境化学 等编委。国家环境基准专家委员会委员，中国土壤学会土壤环境专业委员会委员，长三角区域生态环境保护标准一体化专家咨询委员会委员，上海市环境科学学会理事，上海市化学化工学会环境科学与工程专业委员会副主任，上海市污染场地修复技术研究中心技术委员会主任。

长期致力于土壤地下水污染修复技术、土壤地下水环境多介质界面传输、土壤生物炭固碳技术、绿色友好型环境修复材料等方面的研究。主持国家自然科学基金重点项目/面上项目、国家重点研发计划/重大专项课题、科技部国际合作项目、国家环保行业科研专项课题、上海市科委重大课题以及企业委托等项目。在土壤地下水重金属介质多界面迁移转化及生物地球化学过程研究方面取得了系列创新成果，在Nature Rev. Earth & Environ., Sci. Bull., Environ. Sci. Technol., Water Res.等期刊上发表SCI论文210多篇。建立了土壤重金属化学稳定化、污染土壤地下水一体化、重金属物理分级分离、植物固定与提取等修复技术，并成功应用于射击场、电子加工场地、化工厂、电镀厂等典型污染场地土壤及地下水修复工程10多项。获省部级奖4项，其中教育部自然科学一等奖1项。

主讲课程

《土壤污染控制及修复工程》、《环境学导论》、《环境化学原理》、《高等环境化学》

科研成果

代表性主持科研项目（10项）

1. 国家自然科学基金重点项目（No. 42330706）：土壤-地下水典型重金属多界面转化与迁移过程 （2024-2027）

2. 上海市科委“科技创新行动计划”科技支撑碳达峰碳中和专项项目（No. 22DZ1209400 ）：二氧化碳植物捕获强化调控与土壤长效封存关键技术研究与示范（2022-2025）

3. 国家自然科学基金联合重点项目（No. U1906225）：山东海岸带-近海区域重金属的迁移转化及生态环境效应（2020-2023）

4. 国家自然科学基金面上项目（No. 21777095）：生物炭胶体颗粒物协同土壤Cr(VI)的迁移转化机制与数值模拟（2018-2021）

5. 国家自然科学基金重点项目（No. 21587002）：生物炭与土壤界面的电化学过程及其环境行为（2016-2020）

6. 国家重点研发计划课题（No. 2018YFC1900704）：城市环卫数据采集传输与人工智能分类收运集成技术（2018-2022）

7. 国家重大水专项子课题（No. 2017ZX07204002）：清淤底泥的资源化处置与新材料制备（2017-2020）

8. 国家自然科学基金委面上项目（No. 21377081）：模拟人体消化道内污染土壤重金属铅的形态转化与生物可利用性（2014-2017）

9. 国家自然科学基金面上项目（No. 21077072）：一种双功能吸附剂生物炭同时修复重金属与有机物复合污染土壤的分子机理（2011-2013）

10. 国家自然科学基金面上项目（No. 20877056）：磷酸盐诱导的钝化修复重金属复合污染土壤的作用机制及评估体系（2009-2011）

代表性论文（50篇）

  1. Jun Liang, Xiaoguang Duan, Xiaoyun Xu*, Zehong Zhang, Jingyi Zhang, Ling Zhao, Hao Qiu, Xinde Cao*. 2024 Critical functions of soil components for in situ persulfate oxidation of sulfamethoxazole: Inherent Fe(II) minerals-coordinated nonradical pathway. Environmental Science and Technology. 58, 1, 915-924.

  2. Zehong Zhang, Jia Ren, Jun Liang, Xiaoyun Xu*, Ling Zhao, Hao Qiu, Hi Li, Xinde Cao. 2023 New insight into the natural detoxification of Cr(VI) in Fe-rich surface soil: crucial role of photogenerated silicate-bound Fe(II). Environmental Science and Technology. 57, 21370-21381

  3. Hao Qiu, Ziyang Lou, Xueyuan Gu, Yuanyuan Sun, Jun Wang, Wei Zhang, Xinde Cao*. 2022 Smart 6S roadmap for deciphering the migration and risk of heavy metals in soil and groundwater systems at brownfield sites nationwide in China. Science Bulletin 67, 1295-1299.

  4. Yaqiang Wei, Chengpeng Yuan, Xiaoyun Xu*, Xiang Chen, Zhefan Ren, Xiangyang Gui, Ling Zhao, Hao Qiu, Xinde Cao*. 2022 Colloid formation and facilitated chromium transport in the coastal area soil induced by freshwater and seawater alternating fluctuations. Water Research 218, 118456

  5. Zibo Xu, Yulu Yu, Xiaoyun Xu*, Daniel CW Tsang, Chengbao Yao, Jing Fan, Ling Zhao, Hao Qiu, Xinde Cao. 2022 Direct and Indirect Electron Transfer Routes of Chromium(VI) Reduction with Different Crystalline Ferric Oxyhydroxides in the Presence of Pyrogenic Carbon. Environmental Science and Technology 56, 1724-1735
  6. Jun Liang, Xiaoguang Duan, Xiaoyun Xu*, Kexin Chen, Ying Zhang, Ling Zhao, Hao Qiu, Shaobin Wang, Xinde Cao. 2021 Persulfate Oxidation of Sulfamethoxazole by Magnetic Iron-Char Composites via Nonradical Pathways: Fe(IV) Versus Surface-Mediated Electron Transfer. Environmental Science and Technology 55, 10077-10086.
  7. Jun Liang, Xiaoguang Duan, Xiaoyun Xu*, Kexin Chen, Fan Wu, Hao Qiu, Chengshuai Liu, Shaobin Wang, Xinde Cao. 2021 Biomass-derived pyrolytic carbons accelerated Fe(III)/Fe(II) redox cycle for persulfate activation: Pyrolysis temperature-depended performance and mechanisms. Applied Catalysis B-Environmental 297.
  8. Yaqiang Wei, Xiaoyun Xu*, Ling Zhao, Xiang Chen, Hao Qiu, Bin Gao, Xinde Cao. 2021 Migration and transformation of chromium in unsaturated soil during groundwater table fluctuations induced by rainfall. Journal of Hazardous Materials 416.
  9. Lei Pei, Fan Yang, Xiaoyun Xu*, Hongyan Nan, Xiangyang Gui, Ling Zhao, Xinde Cao. 2021 Further reuse of phosphorus-laden biochar for lead sorption from aqueous solution: Isotherm, kinetics, and mechanism. Science of the Total Environment 792.
  10. Yaqiang Wei, Xinde Cao*. 2021 A COMSOL-PHREEQC Coupled Python Framework for Reactive Transport Modeling in Soil and Groundwater. Groundwater, 60, 284-294.
  11. Zhanhao Wan, Zibo Xu, Yue Sun, Min He, Deyi Hou, Xinde Cao, Daniel CW Tsang*. 2021 Critical Impact of Nitrogen Vacancies in Nonradical Carbocatalysis on Nitrogen-Doped Graphitic Biochar. Environmental Science and Technology 55, 7004-7014
  12. Zhefan Ren, Xiangyang Gui, Yaqiang Wei, Xiang Chen, Xiaoyun Xu, Ling Zhao, Hao Qiu, Xinde Cao*. 2021 Chemical and photo-initiated aging enhances transport risk of microplastics in saturated soils: Key factors, mechanisms, and modeling. Water Research 202, 117407
  13. Xing Li, Erkai He, Bing Xia, C.A.M. van Gestel, W.J.G.M. Peijnenburge, Xinde Cao, Hao Qiu*. 2020 Impact of CeO2 nanoparticles on the aggregation kinetics and stability of polystyrene nanoplastics: Importance of surface functionalization and solution chemistry. Water Research 186, 116324
  14. Jie Ji, Erkai He, Hao Qiu* W.J.G.M. Peijnenburge, C.A.M. van Gestel, Xinde Cao. 2020 Effective Modeling Framework for Quantifying the Potential Impacts of Coexisting Anions on the Toxicity of Arsenate, Selenite, and Vanadate. Environmental Science and Technology 54, 2379-2388.
  15. Ling Zhao*, Dongling Xiao, Yang Liu, Huacheng Xu, Hongyan Nan, Xinde Cao*. 2019 Biochar as simultaneous shelter, adsorbent, pH buffer, and nutrient to promote biodegradation of high concentrations of phenol in wastewater. Water Research 172, 115494.
  16. Xiaoyun Xu, Yuling Zheng, Bin Gao*, Xinde Cao*. 2019 N-doped biochar synthesized by a facile ball-milling method for enhanced sorption of CO2 and reactive red. Chemical Engineering Journal 368, 564-572
  17. Jun Liang, Xiaoyun Xu, Waqas Qamar Zaman, Xiaofang Hu, Ling Zhao, Hao Qiu, Xinde Cao*. 2019 Different mechanisms between biochar and activated carbon for the persulfate catalytic degradation of sulfamethoxazole: Roles of radicals in solution or solid phase. Chemical Engineering Journal 375, 121908
  18. Zibo Xu, Xiaoyun Xu, Xinyi Tao, Chengbo Yao, Daniel C W Tsang. Xinde Cao*. 2019 Interaction with low molecular weight organic acids affects the electron shuttling of biochar for Cr(VI) reduction. Journal of Hazardous Materials 378, 120705
  19. Ling Zhao, Yinghao Zhao, Hongyan Nan, Fan Yang, Hao Qiu, Xiaoyun Xu, Xinde Cao*. 2019 Suppressed formation of polycyclic aromatic hydrocarbons (PAHs) during Fe-preloaded barley straw pyrolysis. Journal of Hazardous Materials 121033
  20. Yue Zhang, Xiaoyun Xu, Pengyu Zhang, Ling Zhao, Hao Qiu, Xinde Cao*. 2019 Pyrolysis-temperature depended quinone and carbonyl groups as the electron accepting sites in barley grass derived biochar. Chemosphere 232, 273~280
  21. Ming Chen, Xinyi Tao, Dengjun Wang, Zibo Xu, Xiaoyun Xu, Xiaofang Hu, Nan Xu, Xinde Cao* 2019 Facilitated transport of cadmium by biochar-Fe3O4 nanocomposites in water-saturated natural soils. Science of the Total Environment 684, 265~275
  22. Fan Yang, Zibo Xu, Yulu Yu, Bin Gao, Xiaoyun Xu, Ling Zhao, Xinde Cao* 2018 Kaolinite enhances the stability of the dissolvable and undissolvable fractions of biochar via different mechanisms. Environmental Science and Technology 52, 8321-8329
  23. Huang Huang, Ying Jiang, Xiaoyun Xu, Xinde Cao* 2018 In vitro bioaccessibility and health risk assessment of heavy metals in atmospheric particulate matters from three different functional areas of Shanghai, China. Science of the Total Environment 610-611, 546-554.
  24. Yihan Dai, Yuan Liang, Xiaoyun Xu, Ling Zhao, Xinde Cao* 2018 An integrated approach for simultaneous immobilization of lead in both contaminated soil and groundwater: Laboratory test and numerical modeling. Journal of Hazardous Materials 342, 107-113
  25. Zibo Xu, Xiaoyun Xu, Daniel CW Tsang, Xinde Cao* 2018 Contrasting impacts of pre- and post-application aging of biochar on the immobilization of Cd in contaminated soils. Environmental Pollution 242, 1362-1370
  26. Ming Chen, Nangual Alim, Yitao Zhang, Nan Xu, Xinde Cao* 2018 Contrasting effects of biochar nanoparticles on the retention and transport of phosphorus in acidic and alkaline soils. Environmental Pollution 239, 562-570.
  27. Xiaoyun Xu, Huang Huang, Yue Zhang, Zibo Xu, Xinde Cao* 2019 Biochar as both electron donor and electron shuttle for the reduction transformation of Cr(VI) during its sorption. Environmental Pollution 244, 423-430
  28. Ming Chen, Dengjun Wang, Fan Yang, Xiaoyun Xu, Nan Xu, Xinde Cao* 2017 Transport and retention of biochar nanoparticles in a paddy soil under environmentally-relevant solution chemistry conditions. Environmental Pollution 230, 540-549.
  29. Xiaoyun Xu, Yinghao Zhao, Jingke Sima, Ling Zhao, Ondrew Masek, Xinde Cao* 2017 Indispensable role of biochar-inherent mineral constituents in its environmental applications: A review. Bioresource Technology 241, 887-899.
  30. Ling Zhao, Zhenliang Ding, Jingke Sima, Xiaoyun Xu, Xinde Cao* 2017 Development of phosphate rock integrated with iron amendment for simultaneous immobilization of Zn and Cr(VI) in an electroplating contaminated soil. Chemosphere 182, 15-21.
  31. Fan Yang, Ling Zhao, Bin Gao, Xiaoyun Xu, and Xinde Cao* 2016 The interfacial behavior between biochar and soil minerals and its effect on biochar stability. Environmental Science and Technology 50, 2264–2271
  32. Xiaoyun Xu, Daxuan Huang, Ling Zhao, Yue Kan, Xinde Cao* 2016 Role of inherent inorganic constituents in SO2 sorption ability of biochars derived from three biomass wastes. Environmental Science and Technology 50, 12957–12965
  33. Ling Zhao, Xinde Cao*, Wei Zheng, John Scott, B. K. Sharma, and Xiang Chen 2016 Co-pyrolysis of biomass with phosphate fertilizers to improve biochar carbon retention, slow nutrient release, and stabilize heavy metals in soil. ACS Sustainable Chemistry and Engineering 4, 1630–1636
  34. Xiaoyun Xu, Yue Kan, Ling Zhao, Xinde Cao* 2016 Chemical transformation of CO2 during its capture by waste biomass derived biochars. Environmental Pollution 213, 533-540
  35. Xiaoyun Xu, A Schierz, Nan Xu, Xinde Cao* 2016 Comparison of the characteristics and mechanisms of Hg(II) sorption by biochar and activated carbon. Journal of Colloid and Interface Science 463, 55–60.
  36. Jingke Sima, Xinde Cao*, Ling Zhao, Qishi Luo 2015 Toxicity characteristic leaching procedure over- or under-estimates leachability of lead in phosphate-amended contaminated soils. Chemosphere 138, 744–750
  37. Feiyue Li, Xinde Cao*, Ling Zhao, Jianfei Wang, Zhenliang Ding 2014 Effects of mineral additives on biochar formation: Carbon retention, stability, and properties. Environmental Science and Technology 48, 11211–11217.
  38. Ling Zhao, Wei Zheng, Xinde Cao* 2014 Distribution and evolution of organic matter phases during biochar formation and their importance in carbon loss and pore structure. Chemical Engineering Journal 250, 240-247.
  39. Ling Zhao, Xinde Cao*, Ondrej Masek 2013 Heterogeneity of biochar properties as a function of feedstock sources and production temperatures. Journal of Hazardous Materials 256-257, 1-9.
  40. Xinde Cao*, Lena Q Ma, Yuan Liang, Bin Gao, Willie Harris. 2011 Simultaneous immobilization of lead and atrazine in contaminated soils using dairy-manure biochar. Environmental Science and Technology 45, 4884-4889
  41. Xinde Cao and Willie Harris* 2010 Properties of dairy manure-derived biochar pertinent to its potential use in remediation. Bioresource Technology 101, 5222-5228
  42. Xinde Cao*, Lena Q Ma, Bin Gao, Willie Harris 2009 Dairy manure-derived biochar effectively sorbs lead and atrazine. Environmental Science and Technology 43, 3285–3291
  43. Xinde Cao, Lena Q Ma* 2009 Immobilization of Cu, Zn, and Pb in contaminated soils using phosphate rock and phosphoric acid. Journal of Hazardous Materials 164, 555-564
  44. Xinde Cao, Willie Harris*. 2008 Carbonate and Magnesium Interactive Effect on Calcium Phosphate Precipitation. Environmental Science and Technology 42, 436-442.
  45. Xinde Cao, Wille G Harris*, MS Josan, VD Nair. 2007 Inhibition of calcium phosphate precipitation under environmentally-relevant conditions. Science of the Total Environment 383, 205-215.
  46. Xinde Cao, Lena Q Ma*, Dean R Rhue, Chip S Appel. 2004 Mechanisms of lead, copper, and zinc retention by phosphate rock. Environmental Pollution 131, 435-444.
  47. Xinde Cao, Lena Q Ma*, Ming Chen, DW Hardison, Willie G Harris. 2003 Lead Transformation and Distribution in the Soils of Shooting Ranges in Florida, USA. Science of the Total Environment 307, 179-189.
  48. Xinde Cao, Lena Q Ma*, Ming Chen, DW Hardison, Willie G Harris. 2003 Weathering of lead bullets and their environmental effects at outdoor shooting ranges. Journal of Environmental Quality 32, 526-534.
  49. Xinde Cao, Lena Q Ma*, A Shiralipour. 2003 Effects of compost and phosphate amendments on arsenic mobility in soils and arsenic uptake by the hyperaccumulator, Pteris vittata, L. Environmental Pollution 126, 157-167.
  50. Xinde Cao, Lena Q Ma* Ming Chen, SP Singh, Willie G Harris. 2002 Impacts of phosphate amendments on lead biogeochemistry at a contaminated site. Environmental Science and Technology, 36, 5296-5304.

荣誉奖励

  • 2021年 上海交通大学“教书育人奖”个人一等奖
  • 2018年 上海市教学成果二等奖（排名第一）
  • 2016年 上海交通大学教学成果特等奖（排名第一）
  • 2011年 上海市“浦江人才”计划获得者
  • 2003年 教育部自然科学一等奖（排名第三）


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